A vessel contains 1.6 g of dioxygen at STP (273.15K, 1 atm pressure). The gas is now transferred to another vessel at constant temperature, where

pressure becomes half of the original pressure. Calculate

(i) volume of the new vessel.

(ii) number of molecules of dioxygen.

Consider the reduction reactions and their equilibrium constants. cu+(aq)+e−↽−−⇀cu(s)pb2+(aq)+2e−↽−−⇀ pb(s)fe3+(aq)+3e−↽−−⇀fe(=6.2×108=4. 0×10−5=9.3×10−3 cu + ( aq ) + e − ↽ − − ⇀ cu ( s ) k =6.2× 10 8 pb 2 + ( aq ) +2 e − ↽ − − ⇀ pb ( s ) k =4.0× 10 − 5 fe 3 + ( aq ) +3 e − ↽ − − ⇀ fe ( s ) k =9.3× 10 − 3 arrange these ions from strongest to weakest oxidizing agent.