Convert 256.3 g sodium carbonate to formula units

Asample of silver (with work function ? = 4.52 ev) is exposed to an ultraviolet light source (? = 200 nm), which results in the ejection of photoelectrons. what changes will be observed if: silver is replaced with copper (? = 5.10 ev) more photoelectrons ejected no photoelectrons are emitted fewer photoelectrons ejected more energetic photoelectrons (on average) less energetic photoelectrons (on average)

The answer for #3 is c but i don't know why

Which buffer would be better able to hold a steady ph on the addition of strong acid, buffer 1 or buffer 2? explain. buffer 1: a solution containing 0.10 m nh4cl and 1 m nh3. buffer 2: a solution containing 1 m nh4cl and 0.10 m nh3