For a gaseous reaction, standard conditions are 298 K and a partial pressure of 1 atm for all species. For the reaction C2H6(g)+H2(g)↽−−⇀2CH4(g) the standard change in Gibbs free energy is ΔG°=−32.8 kJ/mol . What is ΔG for this reaction at 298 K when the partial pressures are PC2H6=0.150 atm , PH2=0.100 atm , and PCH4=0.800 atm ?

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substituting a hydrogen atom with a halogen in a hydrocarbon:

- the single bond remains single. a is wrong.

- the bond with hydrogen is as strong as with a halogen. c is wrong

- a hydrocarbon is saturated if there is no double bond. we do not know that so d is wrong.

- carbon will always have four valence electrons. e is wrong.

by elimination, the correct answer is b. the boiling point of the new compound increases.

c is having 4 valence electrons and is bonded to three hydrogens and one sulphur atom, therefore, the number of bond pair is equal to four. as all the valence electrons are used in forming the bonds so, there is no lone pair left on carbon.

s is having 6 valence electrons and is bonded to one other sulfur atom and one carbon atom, therefore, the number of bond pair is equal to 2. as only two valence electrons are used in forming the bonds so, four electrons are left. therefore, two lone pairs are present on s.