Which reaction will occur if each substance in its standard State? Assume potentials are given in water at 25°C.

acid rain does not usually kill trees directly. instead, it is more likely to weaken the trees by damaging their leaves, limiting the nutrients available to them, or poisoning them with toxic substances slowly released from the soil. the main atmospheric pollutants that affect trees are nitrates and sulphates.

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.