Chemistry, 12.08.2020 05:01, keke6361

Using the standard reduction potentials Ni2+(aq) + 2 e‑Ni(s) ‑0.25 volt Fe3+(aq) + e‑Fe2+(aq) +0.77 volt Calculate the value of E°cell for the cell with the following reaction. Ni2+(aq) + 2 Fe2+(aq) →Ni(s) + 2 Fe3+(aq)

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answered: jayjay9434

The correct answer is - 1.02 V

Explanation:

From the reduction-oxidation reaction:

Ni²⁺(aq) + 2 Fe²⁺(aq) → Ni(s) + 2 Fe³⁺(aq)

Ni²⁺ is reduced to Ni(s) while Fe²⁺ is oxidized to Fe³⁺. Thus, the half reactions are:

Reduction (cathode) : Ni²⁺(aq) + 2 e‑ → Ni(s) Eº= ‑0.25 V

Oxidation (anode) : 2 x (Fe²⁺ → Fe³⁺ + e-)(aq) Eº= -0.77 V

Ni²⁺(aq) + 2 Fe²⁺(aq) → Ni(s) + 2 Fe³⁺(aq)

In order to calculate the Eºcell, we have to add the reduction potential of the reaction in cathode (reduction) to the oxidation potential of the anode (oxidation):

Eºcell= Eºr + Eºo= (-0.25 V) + (-0.77 V) = - 1.02 V

answered: Guest

assuming that your periodic table has eighteen columns, you should highlight the four elements in the third column from the left of the table.

explanation

neutral atoms of elements after calcium contain d electrons. the energy of d orbitals of a particular main shell lies between the energy of the s and p orbitals of the next main shell. for example, electrons in the $3d$ have energy higher than those in the $4 s$ orbital while lower than those of the $4 p$ orbital.

by the aufbau principle, electrons fill orbitals one at a time, starting from those of the lowest energy. the $4s$ orbital is therefore filled right after $3p$ orbitals and before $3 d$ orbitals.

potassium has electron configuration $[\text{ar}] 4 s^{1}$ and calcium $[\text{ar}] 4 s^{2}$ . the s orbital of a main shell holds a maximum of two electrons. the next element would thus have the electron configuration $[\text{ar}] 4 s^{2} \; 3d^{1}$ and satisfy the requirements.

a neutral atom of the element contains three electrons on top of the most recent noble gas element. it should thus be placed in the third column of the periodic table. both scandium and yttrium would satisfy the conditions. an aufbau diagram indicates that the 4f orbital is filled before the 5d. however, it appears that exceptions exists for both lanthanum and actinium. neutral atoms of the two d-block elements also demonstrate the $ns^{2} \; (n-1) p^{1}$ and should be highlighted as well.

answered: Guest

Well to my expert knowledge and my exquisite calculations i think the the negative ion # 412 is the key to sucess

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Using the standard reduction potentials Ni2+(aq) + 2 e‑Ni(s) ‑0.25 volt Fe3+(aq) + e‑Fe2+(aq) +0.77...