What evidence demonstrates that chlorine in the stratosphere is primarily from man-made chemicals rather than from natural sources such as volcanoes?

Chlorine in the stratosphere is primarily from man-made chemicals rather than from natural sources such as volcanoes is evident as follows;

Discussion;

Most of the chlorine in the stratosphere is there as a result of human activities, as the figure below illustrates.

Many compounds containing chlorine are released at the ground.

Volcanoes can emit large quantities of hydrogen chloride, but this gas is rapidly converted to hydrochloric acid, which dissolves in rain water, ice, and snow and does not reach the stratosphere.

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The evidence that demonstrated that the Chlorine in the stratosphere is believed to come primarily from CFCs ( Chlorofluorocarbons) rather than from natural sources such as volcanoes was due to the study conducted in which the amount of chlorine in the stratosphere over the past 20 years was measured and it was discovered that there was an increase over the years. This also corresponded with a rise in CFCs over the same period which shows that the chlorine in the stratosphere was from man made chemicals such as chlorofluorocarbons.

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