What is the effect on the concentrations of NO2-,HNO2,and OH- when HNO2 is added to a solution of KNO2 in water

Answer is: the equilibrium  shifts toward the reactants, to the left side of chemical reaction.it is because lead(ii) nitrate dissociates in water: pb(no₃)₂ → pb²⁺(aq) + 2no₃⁻(aq).according to lechatelier's principle, the position of equilibrium moves to counteract thechange (more lead cations, common ion), the position of equilibrium will move so that the concentration ofproducts decrease and concentration of reactants of chemical reaction increase.read more on -

Vander waals forces are inter molecular bonds that exist within molecules of the same substance. a water molecule is made up of oxygen and hydrogen atoms which share electrons between each other. the vander waals forces are forces that exist between multitude of different  molecules of water. dipole dipole forces is the type of vander waals force that exist in water. the oxygen atom which is more electronegative pulls the shared electron closer to itself thus generating a partial negative charge while the hydrogen acquire a partial positive charge. these two different charges causes attraction to occur in water molecules.