Is combining hydrogen peroxide with manganese dioxide a chemical or physical change?

If you add 5.00 ml of 0.100 m sodium hydroxide to 50.0 ml of acetate buffer that is 0.100 m in both acetic acid and sodium acetate, what is the ph of the resulting solution? acetic acid: ka = 1.8. x 10-5

40dm3 of gas at 760 torr are heated from 5°c to 50°c what is the new volume

Benzonitrile (c6h5cn) is reduced to two different products depending on the reducing agent used. treatment with lithium aluminum hydride followed by water forms k, which has a molecular ion in its mass spectrum at 107 and the following ir absorptions: 3373, 3290, 3062, 2920, and 1600 cm-1. treatment with a milder reducing agent forms l, which has a molecular ion in its mass spectrum at 106 and the following ir absorptions: 3086, 2850, 2820, 2736, 1703, and 1600 cm-1. l shows fragments in its mass spectrum at m/z = 105 and 77. propose structures for k and l and choose an explanation for how this could be concluded.