In which of the following reactions will Kc= Kp?A) 4 NH3(g) + 3 O2(g) ⇌2 N2(g) + 6 H2O(g)B) 2 SO3(g) + 2 NO(g) ⇌2 SO2(g) + 2 NO2(g)C) 4 N2(g) + 2 O2(g) ⇌4 N2O(g)D) 6 SO2(g) + 3 O2(g) ⇌6 SO3(g)E) None of theabove reactions have Kc= Kp

Explanation:

Relation of with is given by the formula:

where,

= equilibrium constant in terms of partial pressure

= equilibrium constant in terms of concentration

R = Gas constant

T = temperature

= change in number of moles of gas particles =

when = 0

a)

= change in number of moles of gas particles =

b)

= change in number of moles of gas particles =

c)

= change in number of moles of gas particles =

d)

= change in number of moles of gas particles =

Thus for reaction , , as = 0

the answer is b. dilution