Chemistry, 03.04.2020 17:29, juliaduenkelsbu

A)Suppose that Li2O is added as an impurity to CaO. If the Li+substitutes for Ca2+, what kind of vacancies would you expect to form? How many of these vacancies are created for every Li+added?(b)Suppose that CaCl2is added as an impurity to CaO. If the Cl-substitutes for O2-, what kind of vacancies would you expect to form? How many of the vacancies are created for every Cl-added?

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answered: Guest

$y = - 4x + 19$

answered: Guest

Idon't know hope someone you

answered: Guest

explanation:

two years ago, when picking flowers in the mountains back of yosemite valley, i found a book. it was blotted and storm-beaten; all of its outer pages were mealy and crumbly. the paper seemed to dissolve like the snow beneath which it had been buried, however; many of the inner pages were well preserved. and although all were more or less stained and torn, whole chapters were easily readable. this is the condition of the great open book of yosemite glaciers today; its granite pages have been torn and blurred by the same storms that wasted the castaway book.

two years ago, when picking flowers in the mountains back of yosemite valley; i found a book. it was blotted and storm-beaten, all of its outer pages were mealy and crumbly. the paper seemed to dissolve like the snow beneath which it had been buried, however, many of the inner pages were well preserved. and although all were more or less stained and torn; whole chapters were easily readable. this is the condition of the great open book of yosemite glaciers today, its granite pages have been torn and blurred by the same storms that wasted the castaway book.

answered: Guest

the missing options are :

(1) lower boiling point and a lower freezing point(2) lower boiling point and a higher freezing point(3) higher boiling point and a lower freezing point(4) higher boiling point and a higher freezing point

answer : the correct answer is option (3) higher boiling point and a lower freezing point

explanation :

when a non volatile solute is added to a solvent like water, it results in elevation of boiling point.

let us find the increase in boiling point of water when cacl₂ is added to water to make a solution of 1 m

step 1 : find molality of the solution

let us assume we have 1 l of solution.

$m = \frac{moles (solute)}{l ( solution)}$

$1 m = \frac{moles (cacl_{2})}{1 l }= 1 mol cacl_{2}$

let us convert this to grams of cacl₂.

molar mass of cacl2 is 111 g/mol

grams of cacl₂ = $1 mol \times \frac{111g}{mol} = 111 g cacl_{2}$

mass of solute = 111 g

assuming density of solution same as water which is 1g/ml we have ,

mass of solution = density * volume

mass of solution = $\frac{1g}{ml} \times 1000 ml = 1000 g$

mass of solution = mass of solvent + mass of solute

mass of solute = 1000g - 111g

mass of solute 889 g = 0.889 kg

the molality of the solution can be calculated as

$molality = \frac{mol (solute)}{kg ( solvent)}$

$molality = \frac{1mol}{0.889kg}$

molality = 1.12 m

step 2 : find boiling point elevation.

the elevation in boiling point is calculated as

$\bigtriangleup t_{b} = i \times k_{b} \times m$

here δtb = boiling point elevation

i = vant hoff factor which is the number of ions formed by the solute .

cacl₂ dissociates as $cacl_{2} \rightarrow ca^{2+} + 2 cl^{-}$

it forms 3 ions . therefore,

i = 3

m = molality which is 1.12 m

kb is constant for a given solvent. for water it is 0.512

$\bigtriangleup t_{b} = 3 \times 0.512 \times 1.12$

$\bigtriangleup t_{b} = 1.7$

the boiling point of water increases by 1.7 °c

step 3: find freezing point depression.

when a non volatile solute is added to water, it results in decrease in freezing point.

the formula to find freezing point depression is

$\bigtriangleup t_{f} = i \times k_{f} \times m$

kf is constant for water and its value is 1.86

$\bigtriangleup t_{f} = 3 \times 1.86 \times 1.12$

$\bigtriangleup t_{f} = 6.2$

the freezing point of water decreases by 6.2 °c

therefore we can say that, the solution will have a higher boiling point and a lower freezing point

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A)Suppose that Li2O is added as an impurity to CaO. If the Li+substitutes for Ca2+, what kind of vac...