A frictionless piston cylinder device is subjected to 1.013 bar external pressure. The piston mass is 200 kg, it has an area of 0.15 m2, and the initial volume of the entrapped ideal gas is 0.12 m3. The piston and cylinder do not conduct heat, but heat can be added to the gas by a heating coil. The gas has a constant-volume heat capacity of 30.1 J/(mol K) and an initial temperature of 298 K, and 10.5 kJ of energy are to be supplied to the gas through the heating coil.

a.) If stops placed at the initial equilibrium position of the piston prevent it from rising, what will be the final temperature and pressure of the gas?
b.) If the piston is allowed to move freely, what will be the final temperature and volume of the gas?

Problem #3 (ch. 1, problem 15)the ideal gas law provides one way to estimate the pressure exerted by a gas on a container. the law isí‘ťí‘ť=푛푛푛푛푛푛푉푉mo re accurate estimates can be made with the van der waals equationí‘ťí‘ť=í‘›í‘›í‘›í‘›í‘›í‘›í‘ ‰í‘‰â’푛푛푟푟â’푞푞푛푛2í‘ ‰í‘‰2where the term nb is a correction for the volume of the molecules and the term an2/v2is a correction for molecular attractions. the values of a and b depend on the type of gas. the gas constant is r, the absolutetemperature is t, the gas volume is v, and the number of moles of gas molecules is indicated by n. if n = 1 mol of an ideal gas were confined to a volume of v = 22.41 l at a temperature of 0â°c (273.2k), it would exert a pressure of 1 atm. in these units, r = 0.0826.for chlorine gas (cl2), a = 6.49 and b = 0.0562. compare the pressure estimates given by the ideal gas law and the van der waals equation for 1 mol of cl2 in 22.41 l at 273.2 k. what is the main cause of the difference in the two pressure estimates, the molecular volume or the molecular attractions?

George is a dalmatian puppy. describe what happens to light that allows you to see george’s black and white coat.

Ageochemist examines a piece of metal that he found in the soil. he performs tests to identify the metal from its density, electrical conductivity, and melting point. which statement best describes his investigation? a. he is determining physical properties that are sufficient to identify the metal. b. he is determining chemical properties that are sufficient to identify the metal. c. he is determining physical properties that are insufficient to identify the metal. d. he is determining chemical properties that are insufficient to identify the metal.