A sample in the laboratory is found to contain 3.36 grams of hydrogen, 20.00 grams of carbon, and 26.64 grams of oxygen. The molecular mass is 180.156 g/mol. Determine both the empirical formula and the molecular formula.

Empirical formula is CH₂O.

Molecular formula = C₆H₁₂O₆

Explanation:

Given data:

Mass of hydrogen = 3.36 g

Mass of carbon = 20.00 g

Mass of oxygen = 26.64 g

Molar mass of compound = 180.156 g/mol

Empirical formula = ?

Molecular formula = ?

Solution:

Empirical formula:

It is the simplest formula gives the ratio of atoms of different elements in small whole number

Number of gram atoms of H = 3.36 / 1.01 = 3.3

Number of gram atoms of O = 26.64 / 16 = 1.7

Number of gram atoms of C = 20 / 12 = 1.7

Atomic ratio:

            C                      :        H            :         O

           1.7/1.7                :     3.3/1.7       :       1.7/1.7

              1                     :           2          :        1

C : H : O = 1 : 2 : 1

Empirical formula is CH₂O.

Molecular formula:

Molecular formula = n (empirical formula)

n = molar mass of compound / empirical formula mass

Empirical formula mass = CH₂O = 12×1 + 2× + 16

Empirical formula mass = 30

n = 180.156 / 30

n = 6

Molecular formula = n (empirical formula)

Molecular formula = 6 (CH₂O)

Molecular formula = C₆H₁₂O₆

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definition

                    entropy is a measure of the randomness or the extent of disorder of a chemical process.

                      enthalpy is a measure of the heat change of a reaction occurring at a constant pressure.

measurement units:

                        entropy is measured in joule per kelvin (jk⁻¹)   whereas enthalpy is measured in joule per mole (jmol⁻¹)

requirements:

                            entropy has no requirements or limits, and its change is measured by the division between the heat change of the chemical process and the temperature.

                              in contrast, enthalpy can only be related to the heat change of the reaction under standard conditions.