At 1 atm, benzene freezes at a temperature of 5.5 °C. Its density changes from 0.879 g/cm3 (liquid) to 0.891 g/cm3 (solid). Benzene enthalpy of fusion is 10.59 kJ/mol. Use the Clapeyron equation to estimate the freezing point of benzene at 1000 atm.

Calculate the expected ph values of the buffer systems from the experiments (a, b,c, d), using the henderson- hasselbalch equation, ph-pka+log[a-]/[ha]. use for pka values carbonic acid= 6.37, and acetic acid= 4.75.

Lem 2 the data below are for the system ethyl propyl ether (1)-chloroform (2) at 0.5 bar. use the data to answer the following questions (all questions refer to p d 0: 5 bar). a) what are the boiling points of the pure components at 0.5 bar? b) a mixture with the overall composition z1 d 0: 1 is brought to 47.6ä±c, 0.5 bar. what is the phase? c) 100 mole of a mixture with z1 d 0: 1 (state a) is mixed with 22 mole of pure ethyl propyl ether vapor (state b). the mixing takes place at 47.6 ä±c, 0.5. bar. what is the phase of the resulting mixture (state c)? if the state is a v/l mixture report the number of moles and mole fractions in each phase. d) plot the txy graph and show states a, b and c. the graph must be done by computer and should be properly annotated. ethyl propyl ether (1) - chloroform (2) at 0.5 bar t ( ä±c) x1 y1 t ( ä±c) x1 y1 42.9 0.000 0.000 49.0 0.470 0.455 43.0 0.020 0.010 49.1 0.520 0.520 43.9 0.065 0.029 48.9 0.567 0.592 45.4 0.156 0.089 48.3 0.652 0.720 46.4 0.215 0.142 47.6 0.745 0.815 47.6 0.296 0.223 46.7 0.822 0.872 48.3 0.362 0.302 45.7 0.907 0.937 48.7 0.410 0.375 44.6 1.000

Salicylic acid is a very important acid. it is used to synthesize the aspirin by treating with acetic anhydride. a 0.2015-g sample of salicylic acid was dissolved in a 100.00-ml volumetric flask, and the solution was diluted to the mark. a 10-ml aliquot of this solution was titrated with standard naoh (0.01130 + 0.2% n) to a phenolphthalein faint pink color end point at 19.81 ml. (a) (calculate the normality of the salicylic acid solution used in the titration. (b) assuming the salicylic acid is pure, what is the equivalent weight of the salicylic acid? practice problems for the final exam (continued) (c) (calculate the inherent error in the determination of the equivalent weight you calculated in part (b). use the following absolute errors in the equipment /glassware when calculating the inherent error. 5.00-ml pipet: + 0.02 ml 100-ml volumetric flask: + 0.08 ml analytical balance: + 0.2 mg 25-ml buret: + 0.03 ml