What is the height of the activation barrier (in kcal/mol to the nearest tenths) of a unimolecular (first-order) process when the observed rate is 105 s-1? Assume that LaTeX: \kappaĪŗ is unity, that Boltzmannās constant is 1.381 x 10-23 J/K, Planckās constant is 6.626 x 10-34 JLaTeX: \cdotā s, the Gas constant is 1.987 x 10-3 kcal/KLaTeX: \cdotā mol, and that the temperature is 298 K. Use the expression from transition-state theory (i. e., the Eyring Equation) given in class, and be careful of units.
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What is the height of the activation barrier (in kcal/mol to the nearest tenths) of a unimolecular (...
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