Chemistry, 11.02.2020 17:24, cam6877

The treatment of a particle in a one-dimensional box can be extended to a rectangular box of dimensions Lx, Ly, and Lz, yielding the following expression for energy.

E = h^2/8m((nx^2/Lx^2) + (ny^2/Ly^2) + (nz^2/Lz^2))

The three quantum numbers nx, ny, and nz independently can assume only integer values.

(a) Determine the energies of the three lowest levels, assuming that the box is cubic.
(b) Determine the degeneracies of all the levels that correspond to the quantum numbers having values of 1 or 2.
E111, E112, E122, E222
(c) How will these degeneracies change in the box where Lx ≠ Ly ≠ Lz?

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The treatment of a particle in a one-dimensional box can be extended to a rectangular box of dimensi...