R = 47.19 [A]*([B]^2)*[C]
Explanation:
The rate law for the reaction 2A + 2B + 2C --> products
Is being sought.
The reaction rate R could be expressed as
R = k ([A]^m)*([B]^n)*([C]^p) (1)
where m, n, and p are the reaction orders with respect to (w.r.t.) components A, B and C respectively. This could be reduced to
R = ka ([A]^m) (2)
Where ka=(k[B]^n)*([C]^p);
R = kb ([B]^n) (3)
Where kb=(k[A]^m)*([C]^p); and
R = kc ([C]^p) (4)
Where kc=(k[A]^m)*([B]^n).
Equations (2), (3) and (4) are obtained for cases when the concentrations of two components are kept constant, while only one component’s concentration is varied. We can determine the reaction wrt each component by employing these equations.
The readability is very much enhanced when the given data is presented in the following manner:
Initial [A] 0.273 0.819 0.273 0.273
Initial [B] 0.763 0.763 1.526 0.763
Initial [C] 0.400 0.400 0.400 0.800
Rate 3.0 9.0 12.0 6.0
Run# 1 2 3 4
Additional row is added to indicate the run # for each experiment for easy reference.
First, we use the initial rate method to evaluate the reaction order w.r.t. each component [A], [B] and [C] based on the equations (2), (3) and (4) above.
Let us start with the order wrt [A]. From the given data, for experimental runs 1 and 2, the concentrations of reactants B and C were kept constant.
Increasing [A] from 0.273 to 0.819 lead to the change of R from 3.0 to 9.0, hence we can apply the relation based on equation (2) between the final rate R2, the initial rate R1 and the final concentration [A2] and the initial concentration [A1] as follows:
R2/R1=ka[A2]^m/ka[A1]^m=([A2]/[A1])^m
9.0/3.0 = (0.819/0.273)^m
3 = (3)^m = 3^1 -> m = 1
Similarly, applying experimental runs 1 and 3 could be applied for the determination of n, by employing equation (3):
R3/R1=kb[B3]^n/kb[B1]^n=([B3]/[B1])^n
12/3= (1.526/0.763)^n
4= 2^n, -> n = 2
And finally for the determination of p we have using runs 4 and 1:
R4/R1=kc[C4]^p/kc[C1]^p=([C4]/[C1])^p
6/3= (0.8/0.4)^p
2= 2^p , -> p = 1
Therefore, plugging in the values of m, n and p into equation (1), the rate law for the reaction will be:
R = k [A]*([B]^2)*[C]
The value of the rate constant k could be estimated by making it the subject of the formula, and inserting the given values, say in run 1:
k = R /( [A]*([B]^2)*[C]) = 3/0.273*(0.763^2)*0.4 =
47.19
Finally, the rate law is
R = 47.19 [A]*([B]^2)*[C]
