What is the empirical formula of sulphur dioxide which contains 50% by mass of sulphur

Harvey kept a balloon with a volume of 348 milliliters at 25.0˚c inside a freezer for a night.  when he took it out, its new volume was 322 milliliters, but its pressure was the same.  if the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer? the temperature of the freezer is  kelvins.

What does an electron configuration for an atom relate to the atoms placement on the periodic table

How many lone pairs of electrons are on the central atom of no3- and what is the molecular shape? one, trigonal planar zero, trigonal pyramidal zero, trigonal planar one, tetrahedral one, trigonal pyramidal