A100 w light bulb is placed in a cylinder equipped with a moveable piston. the light bulb is turned on for 2.0×10−2 hour, and the assembly expands from an initial volume of 0.85 l to a final volume of 5.88 l against an external pressure of 1.0 atm. a)use the wattage of the light bulb and the time it is on to calculate δu in joules (assume that the cylinder and light bulb assembly is the system and assume two significant figures). express your answer using two significant figures. b) calculate w. express your answer using two significant figures. c) calculate q. express your answer using two significant figures.

a) 7.2 × 10³ J

b) -5.1 × 10² J

c) 7.7 × 10³ J

Explanation:

a)Use the wattage of the light bulb and the time it is on to calculate ΔU in joules (assume that the cylinder and light bulb assembly is the system and assume two significant figures). Express your answer using two significant figures.

The light bulb has a power of 100 W (100 J/s) and works during a time of 2.0 × 10⁻² hours. The change in the internal energy (ΔU) is:

b) Calculate w. Express your answer using two significant figures.

We can calculate the work (w) using the following expression.

w = -P . ΔV

where,

P is the external pressure

ΔV is the change in the volume

c) Calculate q. Express your answer using two significant figures.

We can calculate the heat (q) using the following expression.

ΔU = q + w

q = ΔU - w = 7.2 × 10³ J - (-5.1 × 10² J) = 7.7 × 10³ J

the potential energy of the reactants is 200j.

from the energy diagram, the energy of the product formed is 350j; this means that, this reaction is an endothermic reaction, because it absorbs energy from its environment.

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