Consider the formation of [ni(en)3]2+ from [ni(h2o)6]2+. the stepwise δg∘ values at 298 k are δg∘1 for first step=−42.9 kj⋅mol−1 δg∘2 for second step=−35.8 kj⋅mol−1 δg∘3 for third step=−24.3 kj⋅mol−1 calculate the overall formation constant (kf) for the complex [ni(en)3]2+.

kf = 1.16 x 10¹⁸

Explanation:

Step 1: [Ni(H₂O)₆]²⁺  + 1en → [Ni(H₂O)₄(en)]²⁺  ΔG°1 = -42.9 kJmol⁻¹

Step 2: [Ni(H₂O)₄(en)]²⁺  + 1en → [Ni(H₂O)₂(en)₂]²⁺  ΔG°2 = -35.8 kJmol⁻¹

Step 3: [Ni(H₂O)₂(en)₂]²⁺ + 1en →  [Ni(en)₃]²⁺  ΔG°3 = -24.3 kJmol⁻¹

Overall reaction: [Ni(H₂O)₆]²⁺  + 3en → [Ni(en)₃]²⁺  ΔG°r

ΔG°r = ΔG°1 + ΔG°2 + ΔG°3

ΔG°r = -42.9 - 35.8 - 24.3

ΔG°r = -103.0 kJmol⁻¹

ΔG°r = -RTlnKf

-103,000 Jmol⁻¹ =  - 8.31 J.K⁻¹mol⁻¹ x 298 K x lnKf

kf = e ^(-103,000/-8.31x298)

kf = e ^41.59

kf = 1.16 x 10¹⁸

answer

i think the answer is a) as air pressure in an area increases, the density of the gas particles in that area decreases.

hope it

shield volcanos are angry and get mad over the smallest things so much that there heads erupt   pahoehoe and a'a lava. a composite volcano is the poller opposite of a shield volcano. its   peaceful thing and knows how to control its emotions.