What is the value of k, at 25 degrees celsius

Can someone me with 3 and 4 plz. this is for masteries test.

Choose an equation that represents an enzyme-catalyzed reaction. (a) enzyme + substrate → enzyme-substrate complex (b) enzyme + substrate ←−→ enzyme + products (c) enzyme + substrate ←−→ enzyme-substrate complex → enzyme + products (d) enzyme + substrate ←−→ enzyme-substrate complex → enzyme-substrate complex + products

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]