Look at 3b what is the relationship between the period number and the energy level of the d-orbitals

May someone me with these science questions

Ammonium perchlorate nh4clo4 is the solid rocket fuel used by the u. s. space shuttle. it reacts with itself to produce nitrogen gas n2 , chlorine gas cl2 , oxygen gas o2 , water h2o , and a great deal of energy. what mass of nitrogen gas is produced by the reaction of 2.1g of ammonium perchlorate?

In a heat of an engine, if 700 j enters the system, and the piston does 400 j of work what is the final internal (thermal) energy of the system if the initial energy is 1,500 j