Compared to a 0.1 m aqueous solution of nacl, a 0.8 m aqueous solution of nacl has a
(1) higher boiling point and a higher freezing point
(2) higher boiling point and a lower freezing point
(3) lower boiling point and a higher freezing point
(4) lower boiling point and a lower freezing point

If you fill your car tire to a pressure of 32 psi (pounds per square inch) on a hot summer day when the temperature is 35°c (95°f), what is the pressure (in psi) on a cold winter day when the temperature is -15°c (5°f)? assume no gas leaks out between measurements and the volume of the tire does not change.