26.3-2. comparison of differential and flash distillation. a mixture of 100 kg mol that contains 60 mol % n-pentane (a) and 40 mol % nheptane (b) is vaporized at 101.32 kpa pressure under differential conditions until 40 kg mol are distilled. use equilibrium data from example 26.3-2. a. what is the average composition of the total vapor distilled and the composition of the remaining liquid? b. if this same vaporization is done in an equilibrium or flash distillation and 40 kg mol are distilled, what is the composition of the vapor distilled and of the remaining liquid?

Problem #3 (ch. 1, problem 15)the ideal gas law provides one way to estimate the pressure exerted by a gas on a container. the law isí‘ťí‘ť=푛푛푛푛푛푛푉푉mo re accurate estimates can be made with the van der waals equationí‘ťí‘ť=í‘›í‘›í‘›í‘›í‘›í‘›í‘ ‰í‘‰â’푛푛푟푟â’푞푞푛푛2í‘ ‰í‘‰2where the term nb is a correction for the volume of the molecules and the term an2/v2is a correction for molecular attractions. the values of a and b depend on the type of gas. the gas constant is r, the absolutetemperature is t, the gas volume is v, and the number of moles of gas molecules is indicated by n. if n = 1 mol of an ideal gas were confined to a volume of v = 22.41 l at a temperature of 0â°c (273.2k), it would exert a pressure of 1 atm. in these units, r = 0.0826.for chlorine gas (cl2), a = 6.49 and b = 0.0562. compare the pressure estimates given by the ideal gas law and the van der waals equation for 1 mol of cl2 in 22.41 l at 273.2 k. what is the main cause of the difference in the two pressure estimates, the molecular volume or the molecular attractions?

Lem 2 the data below are for the system ethyl propyl ether (1)-chloroform (2) at 0.5 bar. use the data to answer the following questions (all questions refer to p d 0: 5 bar). a) what are the boiling points of the pure components at 0.5 bar? b) a mixture with the overall composition z1 d 0: 1 is brought to 47.6ä±c, 0.5 bar. what is the phase? c) 100 mole of a mixture with z1 d 0: 1 (state a) is mixed with 22 mole of pure ethyl propyl ether vapor (state b). the mixing takes place at 47.6 ä±c, 0.5. bar. what is the phase of the resulting mixture (state c)? if the state is a v/l mixture report the number of moles and mole fractions in each phase. d) plot the txy graph and show states a, b and c. the graph must be done by computer and should be properly annotated. ethyl propyl ether (1) - chloroform (2) at 0.5 bar t ( ä±c) x1 y1 t ( ä±c) x1 y1 42.9 0.000 0.000 49.0 0.470 0.455 43.0 0.020 0.010 49.1 0.520 0.520 43.9 0.065 0.029 48.9 0.567 0.592 45.4 0.156 0.089 48.3 0.652 0.720 46.4 0.215 0.142 47.6 0.745 0.815 47.6 0.296 0.223 46.7 0.822 0.872 48.3 0.362 0.302 45.7 0.907 0.937 48.7 0.410 0.375 44.6 1.000

Asample of ammonia reacts with oxygen as shown. 4nh3(g) + 5o2(g) 4no(g) + 6h2o(g) what is the limiting reactant if 4.0 g of nh3 react with 8.0 g of oxygen? o2 because it produces only 0.20 mol of no. nh3 because it produces only 0.20 mol of no. o2 because it produces two times less no than nh3. nh3 because it produces three times more no than o2.