Methane gas (considered as an ideal gas) undergoes the following sequence of mechanically reversible processes in a closed system: (a) from an initial state of 300 k and 1 bar, it is compressed adiabatically to 350 k (b) it is then cool ed from 350 to 300 k at constant pressure. calculate w. q, au, and ah for each process take cp 36 j/mol. k

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vanderwaal's forces of attraction are the electrostatic intermolecular forces that exist in a molecule due to the temporary or permanent dipoles that are developed in a molecule. in , the major intermolecular forces are dipole-dipole interactions as the molecule is polar (bent structure). so the vanderwaal's forces of interaction in between molecules are the permanent dipole-dipole interactions that develop due to the dipole that exists in between the polar h - s bond. the positively charged hydrogen atom is attracted towards the negative end of the dipole that is sulfur of the adjacent molecule. therefore, these forces of attraction are relatively stronger than that of london dispersion forces that exist in non polar molecules.

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