1.how many ml of 0.523 m hbr are needed to dissolve 8.60 g of caco3?
2hbr(aq) + caco3(s) cabr2(aq) + h2o(l) + co2(g)

2.calculate the number of milliliters of 0.487 m naoh required to precipitate all of the mn2+ ions in 101 ml of 0.628 m mnso4 solution as mn(oh)2. the equation for the reaction is:

mnso4(aq) + 2naoh(aq) mn(oh)2(s) + na2so4(aq)

The answer to your question is:

Explanation:

1.-

HBr = 0.523 M   V = ?

CaCO3 = 8.6 g

                   2HBr(aq) + CaCO₃(s)     ⇒   CaBr₂(aq) + H₂O(l) + CO₂(g)

MW CaCO₃ = 40 + 12 + 48 = 100 g

MW HBr = 80 + 1 = 81 g

Molarity = moles / volume

                          100 g of CaCO₃  1 mol

                            8.6 g                   x

                            x = (8.6 x 1) / 100

                            x = 0.086 moles

                  2 moles of HBr 1 mol of CaCO₃

                 x                          0.086 moles

                 x = (0.086 x 2) / 1 = 0.172 moles of HBr

Volume = moles / molarity

Volume = 0.172/ 0.523 = 0.323 l or 323 ml of HBr

2.-

V = ? ml   NaOH 0.487 M

V = 101 ml of 0.628 M MnSO₄

                 MnSO₄(aq)  +  2NaOH(aq)  ⇒    Mn(OH)₂(s) + Na₂SO₄(aq)

MW MnSO₄ = 55 g

MW NaOH = NaOH = 40 g

Moles = Molarity x volume

Moles = (0.628) x (0.101)

Moles = 0.065 moles of MnSO₄

               1 mol of MnSO₄   2 moles of NaOH

               0.065                   x

               x = (0.065x 2) / 1

              x = 0.131 moles of NaOH

Volume = moles / molarity

Volume = 0.131 / 0.487

Volume = 0.268 l or 268 ml of NaOH