What is the ph of a 3.40 mm of acetic acid, 500 ml in which 50 ml of 1.00 m naoac has been added? ka hoac is 1.8 x 10-5? what percentage of the acid is dissociated?

a) pH = 4.213

b) % dis = 2 %

Explanation:

Ch3COONa → CH3COO- + Na+

CH3COOH ↔ CH3COO- + H3O+

∴ Ka = 1.8 E-5 = ([ CH3COO- ] * [ H3O+ ]) / [ CH3COOH ]

mass balance:

⇒ C CH3COOH + C CH3COONa = [ CH3COOH ] + [ CH3COO- ]

∴ C CH3COOH = 3.40 mM = 3.4 mmol/mL * ( mol/1000mmol)*(1000mL/L)

∴ C CH3COONa = 1.00 M = 1.00 mol/L = 1.00 mmol/mL

⇒ [ CH3COOH ] = 4.4 - [ CH3COO- ]

charge balance:

⇒ [ H3O+ ] + [ Na+ ] = [ CH3COO- ] + [ OH- ]is negligible [ OH-], comes from water

⇒ [ CH3COO- ] = [ H3O+ ] + 1.00

⇒ Ka = (( [ H3O+ ] + 1 )* [ H3O+ ]) / ( 3.4 - [ H3O+])) = 1.8 E-5

⇒ [ H3O+ ]² + [ H3O+ ] = 6.12 E-5 - 1.8 E-5 [ H3O+ ]

⇒ [ H3O+ ]² + [ H3O+ ] - 6.12 E-5 = 0

⇒  [ H3O+ ] = 6.12 E-5 M

⇒ pH = - Log [ H3O+ ] = 4.213

b) (% dis)* mol acid = C CH3COOH = 3.4

∴ mol CH3COOH = 500*3.4 = 1700 mmol = 1.7 mol

⇒ % dis = 3.4 / 1.7 = 2 %

i believe that it is a exoplanet

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :