Chemistry

Chemistry, 26.09.2019 16:30, zhiyar9879

By examining a molecular model of cyclohexane with several all trans-equatorial isopropyl groups and another model with several all-trans-equatorial ethyl groups, adjacent equatorially oriented isopropyl groups experience severe steric interactions which are lacking in the ethyl case due to

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Chemistry, 24.06.2019 07:20, s661103

Identify the more stable stereoisomer in the following pair, and choose the reason that explains your choice. cis− or trans−1−isopropyl−3−methylcyclohexane the more stable stereoisomer is: cis−1−isopropyl−3−methylcyclohexane trans−1−isopropyl−3−methylcyclohexane this is because: cis is more stable than trans in 1,3−disubstituted cyclohexanes. trans−1−isopropyl−3−methylcyclohexane has steric hindrance between the methyl and isopropyl groups. trans is more stable than cis in 1,3−disubstituted cyclohexanes. cis−1−isopropyl−3−methylcyclohexane has steric hindrance between the methyl and isopropyl groups.

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Chemistry, 11.10.2019 19:20, sin16

Assume that you have a variety of cyclohexanes substituted in the positions indicated. identify the substituents as either axial or equatorial. for example, a 1,2-cis relationship means that one substituent must be axial and one equatorial, whereas a 1,2-trans relationship means that either both substituents are axial or both are equatorial. a) 1,5-trans-disubstituted b) 1,6-cis-disubstituted c) 1,2-trans-disubstituted

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Chemistry, 07.11.2019 01:31, deee12345

By examining a molecular model of cyclohexane with several all-trans-equatorial isopropyl groups and another model with several all-trans-equatorial ethyl groups, determine why adjacent equatorially oriented isopropyl groups experience severe steric interactions which are lacking in the ethyl case. draw a chair conformation of the former case which illustrates these severe steric interactions. also draw a newman projection looking down one of the c−c bonds connecting the cyclohexyl ring to an equatorial isopropyl group and illustrate a conformation with severe steric strain. select correct all-equatorial chair conformation of compound 2.

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