Chemistry, 24.06.2019 07:10, cadeduncan71

Which aqueous solution has the highest boiling point at standard pressure? (1) 1.0 m kc1(aq) (3) 2.0 m kcl(aq)(2) 1.0 m cac12(aq) (4) 2.0 m cac12(aq)

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answered: carlosleblanc26

(4) 2.0 M CaCl₂(aq).

Explanation:

Adding solute to water elevates the boiling point.The elevation in boiling point (ΔTb) can be calculated using the relation:

ΔTb = i.Kb.m,

where, ΔTb is the elevation in boiling point.

i is the van 't Hoff factor.

van 't Hoff factor is the ratio between the actual concentration of particles produced when the substance is dissolved and the concentration of a substance as calculated from its mass. For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1.

Kb is the molal elevation constant of water.

m is the molality of the solution.

(1) 1.0 M KCl(aq):

i for KCl = no. of particles produced when the substance is dissolved/no. of original particle = 2/1 = 2.

suppose molarity = molality, m = 1.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (2)(Kb)(1.0 m) = 2(Kb).

(2) 2.0 M KCl(aq):

i for KCl = no. of particles produced when the substance is dissolved/no. of original particle = 2/1 = 2.

suppose molarity = molality, m = 2.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (2)(Kb)(2.0 m) = 4(Kb).

(3) 1.0 M CaCl₂(aq):

i for CaCl₂ = no. of particles produced when the substance is dissolved/no. of original particle = 3/1 = 3.

suppose molarity = molality, m = 1.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (3)(Kb)(1.0 m) = 3(Kb).

(4) 2.0 M CaCl₂(aq):

i for CaCl₂ = no. of particles produced when the substance is dissolved/no. of original particle = 3/1 = 3.

suppose molarity = molality, m = 2.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (3)(Kb)(2.0 m) = 6(Kb).

So, the aqueous solution has the highest boiling point at standard pressure is: (4) 2.0 M CaCl₂(aq).

answered: Guest

answer: the primary difference between a hypothesis and a theory is that b hypothesis is falsifiable, but a theory has been proven to be correct. theory is an explanation of something that is happening but hypothesis is a guess of something that can happen

explanation:

answered: Guest

the balanced equation for reaction of ca metal with o2 to produce cao is as below

2 ca+ o2→ 2 cao2

explanation

the reaction is balanced since the number of atoms in reactant side is equal to number of atoms in product side. for example they are 2 atom of ca in reactant side and 2 atoms of ca in the product side.

the process is a meet the requirement of redox reaction because : calcium is oxidized from oxidation state 0 to 2+ while oxygen is reduced from oxidation state 0 to 2-

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Which aqueous solution has the highest boiling point at standard pressure? (1) 1.0 m kc1(aq) (3) 2.0...