Calculate the pka of hypochlorous acid. the ph of a 0.015 m solution of hypochlorous acid has a ph of 4.64.

Explanation:

1) Data:

a) Hypochlorous acid = HClO

b) [HClO} = 0.015

c) pH = 4.64

d) pKa = ?

2) Strategy:

With the pH calculate [H₃O⁺], then use the equilibrium equation to calculate the equilibrium constant, Ka, and finally calculate pKa from the definition.

3) Solution:

a) pH

b) Equilibrium equation: HClO (aq) ⇄ ClO⁻ (aq) + H₃O⁺ (aq)

c) Equilibrium constant: Ka =  [ClO⁻] [H₃O⁺] / [HClO]

d) From the stoichiometry: [CLO⁻] = [H₃O⁺] = 2.29 × 10 ⁻⁵ M

e) By substitution: Ka = (2.29 × 10 ⁻⁵ M)² / 0.015M = 3.50 × 10⁻⁸ M

f) By definition: pKa = - log Ka = - log (3.50 × 10 ⁻⁸) = 7.46

answer: the rate of diffusion increases with increase in temperature.

increase in temperature, increases the molecular/particles speed (kinetic energy. diffusion means movement of particles through the material.

generally, the heavier the particle the more it interacts with the environment and more the temperature matters. so higher temperature results in higher diffusion.