Me with due in 2
on a summer day, you take a road trip through moses lake, wa, in a sports car. you start out at a temperature of 21°c in the morning, but the temperature in moses lake will reach a peak of 55°c. each tire on your car holds 15.2 l of nitrogen gas at a starting pressure of 247 kpa. the tires will burst if the internal pressure exceeds 270 kpa. answer the following questions and show your work. r = 8.31

o how many moles of nitrogen gas are in each tire?

o what would the maximum tire pressure be at 50 degrees c?

o will the tires burst in moses lake? explain.

o if you must let nitrogen gas out of the tire before you go, to what pressure must you reduce the tires before you start your trip? (assume no significant change in tire volume.)

1- 1.54 mol.

2- 271.9 kPa.

3- Yes, the tires will burst.

4- 235.67 kPa.

Explanation:

Q1- How many moles of nitrogen gas are in each tire?  

where, P is the pressure of the nitrogen gas (P = 247.0 kPa/101.325 = 2.44 atm),

V is the volume of the nitrogen gas (V = 15.2 L),

n is the no. of moles of the nitrogen gas (n = ??? mole),

R is the general gas constant (R = 0.082 L.atm/mol.K),

T is the temperature of the nitrogen gas (T = 21°C + 273 = 294 K).

∴ n = PV/RT = (2.44 atm)(15.2 L)/(0.082 L/atm/mol.K)(294.0 K) = 1.54 mol.

Q2: What would the maximum tire pressure be at 50 degrees C?  

∴ P = nRT/V = (1.54 atm)(0.082 L/atm/mol.K)(323.0 K)/(15.2 L) = 2.68 atm = 271.9 kPa.

Q3: Will the tires burst in Moses Lake? Explain.

Yes, the tires will burst because the internal pressure be 271.9 kPa that exceeds 270 kPa, the pressure above which the tires will burst.

Q4: If you must let nitrogen gas out of the tire before you go, to what pressure must you reduce the tires before you start your trip? (Assume no significant change in tire volume.)  

T = 55°C + 273 = 328 K,

Pressure = 270 kPa (the pressure above which the tires will burst). (P =270 kPa/101.325 = 2.66 atm).

V = 15.2 L, as there is no significant change in tire volume.

∴ n = PV/RT = (2.66 atm)(15.2 L)/(0.082 L.atm/mol.K)(328 K) = 1.5 mol.

1.5562 moles of N₂ in the tires will give a pressure of 270 kPa at 55°C, so this is the minimum moles of N₂ that will make the tires burst.

P = ???  

V = 15.6 L.

n = 1.5 mol

T = 21°C + 273 = 294.0 K  

R = 0.0821 L.atm/mol.K.

∴ P = nRT/V = (1.5 mol x 0.082 x 294.0 K) / (15.6 L) = 2.2325 atm = 235.67 kPa.

So, the starting pressure needs to be 235.67 kPa or just under in order for the tires not to burst.

the electronic configuration of an atom with eight electrons is 1s²2s²2p⁴. the orbital diagrams are shown in the figure.

as per the hunds rule:

1. electrons tend to avoid being in the same orbital as per as practicable.

2. electrons in different orbitals of the same energy will have their spin parallel.

this can be illustrated from the multiplicity of the orbitals of the atom. as there are four electrons in the p orbital and p orbital has 3 sub-shells. the electrons can be fed in different ways as shown in the figure but the correct orbital diagram will be as per the hunds rule.

for points guys