Who discovered a pattern to the elements in 1869?

The Russian chemist Dimitri Mendeleev.

At that time the periodic table listed the elements in order of arranging by atomic mass. (the number of protons in the nucleus of an atom).  

it's filtration, but this is an assumption so my apologies if i got this

  the   balanced   equation   for   reaction of   ca metal   with   o2 to   produce   cao   is as below

2 ca+ o2→ 2 cao2

  explanation

the reaction is   balanced     since the   number of atoms   in reactant side is   equal to   number of atoms   in   product side.   for   example   they   are 2   atom of   ca in   reactant   side   and   2   atoms of ca   in   the product side.

  the   process   is a   meet the   requirement   of   redox   reaction because :     calcium   is   oxidized   from   oxidation state 0   to 2+   while   oxygen   is reduced from   oxidation   state   0   to 2-