Chemistry, 05.07.2019 03:00, priceisright11401

Describe the trends in first ionization energy within groups and across periods in the periodic table. provide examples.

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answered: smiley29162

Within Groups: Ei decreases from top to bottom

Across Periods: Ei Increases from left to right

Explanation:

Ionization Energy is defined as, "the minimum amount of energy required to remove the valence electron from the valence shell of an atom in its gaseous state".

Trends in Periodic table:

Across Periods:

Ionization Energy increases from left to right along the periods because moving from left to right in the same period the number of protons (atomic number) increases but the number of shells remain constant hence, resulting in strong nuclear interactions and electrons are more attracted to nucleus hence, requires more energy to knock them out.

Within Groups:

Ionization energy decreases from top to bottom along the groups because the number of shells increases and the distance between nucleus and valence electrons also increases along with increase in shielding effect provided by core electrons. Therefore, the valence electrons experience less nuclear attraction and are easily removed.

answered: Guest

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction: so₂cl₂ (g) = so₂ (g) + cl₂ (g) total

the moles at equilibrium: 1 - α α α = 1+α

concentrations: 1 - α α α = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

$k_{c}$ = $\frac{[so2cl2] x [cl2]}{[so2cl2]}$

or, $\frac{\alpha ^{2} }{(1-\alpha)v }$

or, $k_{c}$ = $\frac{\alpha ^{2} }{(1-\alpha) }$ (at v = 1l)

the reaction: so₂cl₂ (g) = so₂ (g) + cl₂ (g) total

the moles at equilibrium: 1 - α α α = 1+α

concentrations: (1 - α)/0.5 α/0.5 α/0.5 = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

$\frac{[so2cl2] x [cl2]}{[so2cl2]}$

or, $\frac{\alpha ^{2} }{(1-\alpha)0.5 }$

$\frac{\alpha ^{2} }{(1-\alpha) }$ = $\frac{\alpha ^{2} }{(1-\alpha) 0.5}$

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

answered: Guest

the dissolution of polymer can be thermodynamically described in 2 steps.

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Describe the trends in first ionization energy within groups and across periods in the periodic tabl...