The following equation shows the conversion of ethanol c2h5oh in a wine sample into acetic acid c2h4o2 through the action of oxygen from air c2h5oh+o2-> c2h4o2+h2o this reaction drastically changes the taste of the wine. if 100.0ml of wine initially contained 12.0g of ethanol, and after a period of time 4.00g of acetic acid were detected, what percent of the ethanol had been converted?

Given:

Volume of wine = 100 ml

Initial Mass of ethanol = 12.0 g

Mass of acetic acid formed = 4.00 g

To determine:

% ethanol converted to acetic acid

Explanation:

Molar mass of C2H5OH (ethanol) = 46 g/mol

Molar mass of C2H4O2 (acetic acid) = 60 g/mol

The reaction of ethanol in air is:

C2H5OH + O2 → C2H4O2 + H2O

Based on the stoichiometry: 1 mole of ethanol produces 1 mole of acetic acid

Moles of ethanol initially present = mass of ethanol/molar mass

= 12/46 = 0.2609 moles

Moles of acetic acid produced = moles of ethanol converted

= 4/60 = 0.0667 moles

Mass of ethanol converted = Moles of ethanol * molar mass

= 0.0667 * 46 = 3.07 g

% ethanol converted = (mass of ethanol converted/initial mass )*100

% converted = (3.07/12.0) *100 = 25.6%

Ans: 25.6% of ethanol gets converted to acetic acid

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

they vary. it used to be meat, grain, bread, candy, beverages, donuts, and fruits/vegetables. now they added exercise in.