If 10 moles of h2o are produced how many moles of co2 are also produced.

When will le chatelier's principle come into effect? at the beginning of a reaction, when there are only reactants when a reaction has reached chemical equilibrium when a catalyst is added to a reaction mixture when a reaction is occurring but not yet at equilibrium

The answer for #3 is c but i don't know why

Kc = 0.040 for the system below at 450oc. if a reaction is initiated with 0.40 mole of cl2 and 0.40 mole of pcl3 in a 2.0 liter container, what is the equilibrium concentration of cl2 in the same system? pcl5(g) ⇄ pcl3(g) + cl2(g)