How does the structure of ionic bonds affect the structure of ionic compounds

Consider the following reactions. (note: (s) = solid, (l) = liquid, and (g) = gas.) mg(s) + ½o2(g) → mgo(s) + 146 kcal/mole h2(g) + ½o2(g) → h2o(g), δh = -57.82 kcal/mole what type of reaction is represented by the previous two examples?

Amixture initially contains a, b, and c in the following concentrations: [a] = 0.300 m , [b] = 1.05 m , and [c] = 0.550 m . the following reaction occurs and equilibrium is established: a+2b⇌c at equilibrium, [a] = 0.140 m and [c] = 0.710 m . calculate the value of the equilibrium constant, kc.

Why is it that 85.48 rounded to two significant figures is 85 and not 86?