Biology, 17.12.2020 17:10, khorasanpublic

Carbohydrates like glucose can undergo spontaneous rearrangement to give an alternate configuration for the anomeric carbon when the ring is free in solution. However, when glucose is covalently attached to another sugar through C1, this rearrangement cannot occur. Consequently, the configuration of carbohydrate oligomers and polymers is fixed. Why can't glucose rearrange when in a polymer form?

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Carbohydrates like glucose can undergo spontaneous rearrangement to give an alternate configuration...