Which of the following was likely present in earth's early atmosphere over four billion years ago?

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there is no

explanation:

the "dirty dozen" chemicals banned in an international treaty are formally known as persistent organic pollutants, or pops. the united nations environment program provided this background on what they are and what they can do to humans and wildlife.

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sulfur dioxide

explanation: acid rain is caused by a chemical reaction that begins when compounds like sulfur dioxide and nitrogen oxides are released into the air. these substances can rise very high into the atmosphere, where they mix and react with water, oxygen, and other chemicals to form more acidic pollutants, known as acid rain.